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| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Basic information | | Reaction |
| Product Name: | DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) | | Synonyms: | (S)-(-)-2,2''-Bis-(diphenylphosphino)-1,1''-binaphthyl ruthenium dichloride;[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride;Dichloro〔(S)-(－)-2,2-bis(diphenylphosphino)-1,1-binaphthyl〕ruthenium(Ⅱ);Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(S)-BINAP]RuCl2;(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium;-binaphthyl]dichlororuthenium;-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% | | CAS: | 134524-84-8 | | MF: | C44H32Cl2P2Ru | | MW: | 794.65 | | EINECS: | 634-379-4 | | Product Categories: | Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Ru | | Mol File: | 134524-84-8.mol |
| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties |
| Melting point | >300 ºC | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | solubility | Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated) | | form | Powder | | color | orange | | Sensitive | air sensitive | | Stability: | Air Sensitive, Moisture Sensitive |
| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Usage And Synthesis |
| Reaction |
- Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
- Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
| | Chemical Properties | Solid | | Uses | [(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters. |
| DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials |
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![DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)](/img/134524-84-8.jpg "DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)")
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