DIMETHYL 3-METHYLGLUTARATE
DIMETHYL 3-METHYLGLUTARATE
  • CAS No.:19013-37-7
Other grades of this product :
DIMETHYL 3-METHYLGLUTARATE Basic information
Product Name:DIMETHYL 3-METHYLGLUTARATE
Synonyms:DIMETHYL 3-METHYLGLUTARATE;3-METHYL-PENTANEDIOIC ACID DIMETHYL ESTER;Dimethyl 3-methylpentanedioate;Glutaric acid, 3-methyl-, dimethyl ester;Methyl 3-methylgutarate;3-Methylglutaric acid dimethyl;3-Methylglutaric acid dimethyl ester;3-Methylpentanedioic acid dimethyl
CAS:19013-37-7
MF:C8H14O4
MW:174.19
EINECS:200-258-5
Product Categories:C8 to C9;Carbonyl Compounds;Esters
Mol File:19013-37-7.mol
DIMETHYL 3-METHYLGLUTARATE Chemical Properties
Boiling point 110 °C/19 mmHg (lit.)
density 1.052 g/mL at 25 °C (lit.)
refractive index n20/D 1.425(lit.)
Fp 207 °F
CAS DataBase Reference19013-37-7(CAS DataBase Reference)
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
DIMETHYL 3-METHYLGLUTARATE Usage And Synthesis
UsesDimethyl 3-methylglutarate may be used in the synthesis of (R)- and (S)-4-amino-3-methylbutanoic acids, via initial enantioselective hydrolysis with pig liver esterase. It may be used in the preparation of optically active form of verrucarinic acid derivative. It may be used as building block for chemoenzymatic asymmetric synthesis.
Synthesis Reference(s)The Journal of Organic Chemistry, 59, p. 2132, 1994 DOI: 10.1021/jo00087a033Tetrahedron Letters, 26, p. 5643, 1985 DOI: 10.1016/S0040-4039(01)80908-4
General DescriptionDimethyl 3-methylglutarate is an ester. It participates in the synthesis of (R,Z)- muscenone, a valuable perfume ingredient.
DIMETHYL 3-METHYLGLUTARATE Preparation Products And Raw materials
Preparation Products2-METHYL-1,3-PROPANEDIOL-->(1S,2S)-2-Methylcyclopropane-1-carboxylic acid

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