[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
  • CAS No.:18498-01-6
Other grades of this product :
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Basic information
Reactions
Product Name:[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
Synonyms:1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),Min.97%;1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),97% (DPPE)CoCl2;Dichloro[ethylenebis[diphenylphosphine]]cobalt;[1,2-BIs(diphenylphosphino);ethane]dichlorocobalt(II);(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt;[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II);[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ)
CAS:18498-01-6
MF:C26H26Cl2CoP2
MW:530.27
EINECS:
Product Categories:Co;Catalysis and Inorganic Chemistry;API intermediates;Chemical Synthesis;Cobalt;metal-phosphine complex
Mol File:18498-01-6.mol
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Chemical Properties
Melting point 260 °C (dec.)(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color green
Water Solubility Insoluble in water.
Sensitive Hygroscopic
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Usage And Synthesis
Reactions
  1. Catalyst used for the hydrovinylation of styrene.
  2. Cobalt-catalyzed hydroalkylation of [60] fullerene with active alkyl bromides.
  3. Cobalt-catalyzed 1,4-addition of organoboronic acids to activated alkenes. 
UsesDichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II) is used as a catalyst for regio- and stereoselective intermolecular enzyme coupling, cross-coupling reactions of alkyl halides with aryl Grignard reagents, hydrovinylation of styrene, tandem radical cyclization and cross-coupling, dimethylation, hydrodechlorination and addition reactions.
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Preparation Products And Raw materials

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