LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
  • CAS No.:175923-07-6
Other grades of this product :
LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Basic information
Reactions
Product Name:LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
Synonyms:LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE];LANTHANUM TRIS(HEXAMETHYLDISILAZIDE);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDO]LANTHANUM;TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]LANTHANUM (III);TrisN,N-bis(trimethylsilyl)amideülanthanum(III), 97%;Lanthanum (III) tris[N,N-bis(trimethylsiyl)amide] 99,9%;Tris[N,N-bis(trimethylsilyl)amide]lanthanum(Ⅲ);Tris(N,N-bis(trimethylsilyl)amide)lanthanum (III), 98+% (99.9%-La) (REO)
CAS:175923-07-6
MF:C18H54LaN3Si6
MW:620.06
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Lanthanum;LanthanumVapor Deposition Precursors;Precursors by Metal;organometallic complex
Mol File:175923-07-6.mol
LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Chemical Properties
Melting point 149-153 °C(lit.)
Fp 36 °F
form Powder
color white
Sensitive Air & Moisture Sensitive
Safety Information
Hazard Codes F,C
Risk Statements 11-14/15-34
Safety Statements 16-26-36/37/39-43-45-7/8
RIDADR UN 3396 4.3/PG 2
WGK Germany 3
HazardClass 4.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Usage And Synthesis
Reactions
  1. Catalyst precursor for enantioselective intramolecular hydroamination of aminoalkenes and aminodienes. 
  2. Catalyzes a mild and highly selective addition of terminal alkynes to nitriles to form conjugated ynones.
  3. Catalytic amidation of aldehydes with amines. 
LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Preparation Products And Raw materials

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