(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
  • CAS No.:16854-32-3
Other grades of this product :
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Basic information
Product Name:(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Synonyms:2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol;[S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol;L-THIOMICAMINE;(1S,2S)-(+)-THIOMICAMINE;(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL;thiomicamine;(1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol
CAS:16854-32-3
MF:C10H15NO2S
MW:213.3
EINECS:240-878-4
Product Categories:
Mol File:16854-32-3.mol
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Chemical Properties
Melting point 151-154 °C(lit.)
Boiling point 428.2±45.0 °C(Predicted)
density 1.25±0.1 g/cm3(Predicted)
pka11.75±0.45(Predicted)
optical activity[α]25/D +25°, c = 1 in ethanol
CAS DataBase Reference16854-32-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 2930909899
MSDS Information
ProviderLanguage
SigmaAldrich English
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Usage And Synthesis
Uses(1S,2S)-(+)-Thiomicamine can be used:
  • As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
  • As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
  • As a chiral base in the resolution of an angiotensin II type 2 receptor [AT2R] antagonist named EMA401.
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Preparation Products And Raw materials

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