| 4-(TERT-BUTYLDIMETHYLSILYLOXY)PHENYLBORONIC ACID Basic information |
| Product Name: | 4-(TERT-BUTYLDIMETHYLSILYLOXY)PHENYLBORONIC ACID |
| Synonyms: | oxy)phenyL;4-(T-BUTYL DIMETHYLSILOXY) PHENYL BORONIC ACID;4-(TERT-BUTYL DIMETHYLSILOXY)PHENYL BORONIC ACID;4-(TERT-BUTYLDIMETHYLSILYLOXY)PHENYLBORONIC ACID;4-(TERT-BUTYLDIMETHYLSILYOXY)PHENYLBORONIC ACID;AKOS BRN-0412;4-(TERT-BUTYLDIMETHYLSILYOXY)PHENYLBORON;4-(tert-Butyldimethylsilyloxy)benzeneboronic acid |
| CAS: | 159191-56-7 |
| MF: | C12H21BO3Si |
| MW: | 252.19 |
| EINECS: | |
| Product Categories: | blocks;BoronicAcids;Aryl;Organoborons;Boronic acid;Boronic Acids;Boronic Acids;Boronic Acids and Derivatives;Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents |
| Mol File: | 159191-56-7.mol |
| 4-(TERT-BUTYLDIMETHYLSILYLOXY)PHENYLBORONIC ACID Chemical Properties |
| Melting point | 194-198 °C (lit.) |
| Boiling point | 321.4±44.0 °C(Predicted) |
| density | 1.01±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | powder to crystal |
| pka | 8.68±0.16(Predicted) |
| color | White to Almost white |
| Safety Information |
| Hazard Codes | Xi |
| WGK Germany | 3 |
| HS Code | 2931900090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| 4-(TERT-BUTYLDIMETHYLSILYLOXY)PHENYLBORONIC ACID Usage And Synthesis |
| Uses | Reactant involved in:• ;Asymmetric addition reactions with β-substituted cyclic enones1• ;Hydroarylation and heterocyclization with phenylpropiolates2• ;Double Suzuki-Miyaura coupling reactions3Starting material for the synthesis of red electroluminescent polyfluorenes4Reactant involved in the synthesis of biologically active molecules including:• ;Phenylpyridone derivatives as MCH1R antagonists5• ;Atromentin and its O-alkylated derivatives3• ;Gelatinases and MT1-MMP inhibitors6 |
| Uses | Reactant involved in:
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| 4-(TERT-BUTYLDIMETHYLSILYLOXY)PHENYLBORONIC ACID Preparation Products And Raw materials |
| Raw materials | (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE-->Triisopropyl borate-->tert-Butyldimethylsilyl chloride-->4-Hydroxyphenylboronic acid-->4-Bromophenol-->Trimethyl borate |
| Preparation Products | 4-Hydroxy-4'-fluorobiphenyl |
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