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| 2-METHYL-3-PHENYL-2-PROPEN-1-OL Basic information |
| 2-METHYL-3-PHENYL-2-PROPEN-1-OL Chemical Properties |
| Melting point | 24-25 °C(Solv: ligroine (8032-32-4)) | | Boiling point | 77 °C0.1 mm Hg(lit.) | | density | 1.03 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.572(lit.) | | Fp | >230 °F | | pka | 14?+-.0.10(Predicted) | | form | powder to lump to clear liquid | | color | White or Colorless to Light yellow | | EPA Substance Registry System | 2-Propen-1-ol, 2-methyl-3-phenyl- (1504-55-8) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 2 | | RTECS | GE2340000 | | HS Code | 2906290090 | | toxicity | The acute oral LD50 in rats was reported as 2.4 ml/kg (1.9-3.0 ml/kg) (Levenstein, 1974). The acute dermal LD50 in rabbits exceeded 5 g/kg (Levenstein, 1974). |
| 2-METHYL-3-PHENYL-2-PROPEN-1-OL Usage And Synthesis |
| Occurrence | Has apparently not been reported to occur in nature | | Uses | trans-2-Methyl-3-phenyl-2-propen-1-ol was used in the preparation of 5-methyl-4-phenyl-5-hexen-2-one. | | Preparation | By selective hydrogenation of methylcinnamic aldehyde | | Synthesis Reference(s) | Journal of the American Chemical Society, 117, p. 10417, 1995 DOI: 10.1021/ja00146a041 | | Metabolism | Cinnamic alcohol is mainly metabolized to benzoic acid, presumably via cinnamic acid, but substitution apparently prevents oxidation to benzoic acid, since 2-ethylcinnamic alcohol ( C 6H 5CH:C(C 2H 5)CH 2O H ) is partly (30-33%) excreted as α-ethylcinnamic acid (Williams, 1959) |
| 2-METHYL-3-PHENYL-2-PROPEN-1-OL Preparation Products And Raw materials |
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