2-Hydroxybenzophenone One Chongqing Chemdad Co. ，Ltd

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2-Hydroxybenzophenone

CAS No.：117-99-7

Other grades of this product :

2-Hydroxybenzophenone Basic information

Product Name:	2-Hydroxybenzophenone
Synonyms:	(2-Hydroxy-phenyl)-phenylmethanon;2-Hydroxybenzophenone99%;2-HYDROXYBENZOPHENONE 99%;2-Hydroxybenzophenone, 99% 1GR;2-Hydroxybenzophenone, 99% 25GR;(2-hydroxyphenyl)phenyl-methanon;(2-hydroxyphenyl)phenylmethanone;(2-Hydroxy-phenyl)-phenylmethanone
CAS:	117-99-7
MF:	C13H10O2
MW:	198.22
EINECS:	204-226-2
Product Categories:	Aromatic Benzophenones & Derivatives (substituted);API intermediates;Linkers for Solid Phase Synthesis;C13 to C14;Carbonyl Compounds;Ketones
Mol File:	117-99-7.mol

2-Hydroxybenzophenone Chemical Properties

Melting point	37-39 °C (lit.)
Boiling point	171-173 °C/12 mmHg (lit.)
density	1.1184 (rough estimate)
refractive index	1.5954 (estimate)
Fp	>230 °F
storage temp.	Sealed in dry,2-8°C
pka	8.07±0.30(Predicted)
form	Crystalline Powder
color	Yellow
Water Solubility	insoluble
BRN	1638174
CAS DataBase Reference	117-99-7(CAS DataBase Reference)
NIST Chemistry Reference	Methanone, (2-hydroxyphenyl)phenyl-(117-99-7)
EPA Substance Registry System	Methanone, (2-hydroxyphenyl)phenyl- (117-99-7)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39-36
WGK Germany	3
TSCA	Yes
HazardClass	IRRITANT
HS Code	29145000

MSDS Information

Provider	Language
2-Hydroxybenzophenone	English
ACROS	English
SigmaAldrich	English
ALFA	English

2-Hydroxybenzophenone Usage And Synthesis

Chemical Properties	yellow crystalline powder
Uses	UV absorber in plastics.
Uses	2-Hydroxybenzophenone was used to quantify the metabolites of unmethylated extracts from the supernatants of Pseudomonas acidovorans cultures grown on 1,1-diphenylethylene.
Application	2-Hydroxybenzophenone was used to quantify the metabolites of unmethylated extracts from the supernatants of Pseudomonas acidovorans cultures grown on 1,1-diphenylethylene.2-Hydroxybenzophenone forms copolymer 2-hydroxy, 3-allyl, 4,4′-dimethoxybenzophenone with methyl methacrylate.It forms photostabilizer compounds with 2,2,6,6-tetramethylpiperidine under phase transfer catalysis conditions.It reacts with 3-aminophenyl boronic acid to form macrocyclic boronates.
Preparation	Preparation by Friedel–Crafts acylation of benzene in the presence of aluminium chloride, ? with 2-hydroxybenzoyl chloride (salicylic acid chloride), (52%), (39%), at temperature <60°; ? with o-anisoyl chloride. Demethylation occurred during the Friedel–Crafts acylation, especially in the presence of ferric chloride at 130–140°; ? with 2-ethoxybenzoyl chloride in a boiling water bath (42%).
Synthesis Reference(s)	Journal of the American Chemical Society, 76, p. 5469, 1954 DOI: 10.1021/ja01650a062The Journal of Organic Chemistry, 32, p. 3844, 1967 DOI: 10.1021/jo01287a027
General Description	2-Hydroxybenzophenone forms copolymer 2-hydroxy, 3-allyl, 4,4′-dimethoxybenzophenone with methyl methacrylate. It forms photostabilizer compounds with 2,2,6,6-tetramethylpiperidine under phase transfer catalysis conditions. It reacts with 3-aminophenyl boronic acid to form macrocyclic boronates.

2-Hydroxybenzophenone Preparation Products And Raw materials

Raw materials	4-Hydroxybenzophenone-->2-[hydroxy(phenyl)methyl]phenol-->2(3H)-Benzofuranone,3-phenyl--->2-IODOBENZOPHENONE-->2-(ACETYLOXY)-BENZALDEHYDE-->3-HYDROXYBENZOPHENONE-->CHROMONE-3-CARBOXALDEHYDE-->Phenylboronic acid-->Phenol-->Crotonaldehyde-->Iodobenzene-->2-Iodophenol-->2-Methylbenzyl alcohol
Preparation Products	2-Hydroxydiphenylmethane

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