DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE
DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE
  • CAS No.:13031-04-4
Other grades of this product :
DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE Basic information
Product Name:DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE
Synonyms:dihydro-4,4-dimethylfuran-2,3-dione;DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE;keto-pantoyllactone;4,4-Dimethyl-4,5-dihydro-2,3-furandione;4,4-Dimethyl-4,5-dihydrofuran-2,3-dione;4,4-Dimethyloxolane-2,3-dione;4,4-Dimethyltetrahydrofuran-2,3-dione;Ketopantolactone
CAS:13031-04-4
MF:C6H8O3
MW:128.13
EINECS:235-891-7
Product Categories:API intermediates;Building Blocks;Furans;Heterocyclic Building Blocks
Mol File:13031-04-4.mol
DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE Chemical Properties
Melting point 67-69 °C (lit.)
Boiling point 125-126℃ (15 Torr)
density 1.152±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility dichloromethane: soluble25mg/mL, clear, colorless to yellow
form Solid
color Pale Beige
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
DIHYDRO-4,4-DIMETHYL-2,3-FURANDIONE Usage And Synthesis
Synthesis Reference(s)Synthetic Communications, 14, p. 697, 1984 DOI: 10.1080/00397918408063756
General DescriptionDihydro-4,4-dimethyl-2,3-furandione is an activated keto compound and its enantioselective hydrogenation was reported. Neutral Rhodium (I) aminophosphine-phosphinite complex calatyzed asymmetric hydrogenation of dihydro-4,4-dimethyl-2,3-furandione was reported. Asymmetric hydrogenation of dihydro-4,4-dimethyl-2,3-furandione gives D-(-)-pantoyl lactone, a key intermediate in the synthesis of pantothenic acid.

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