N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
  • CAS No.:129986-67-0
Other grades of this product :
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Basic information
Product Name:N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
Synonyms:N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE;N-METHOXY-N-METHYL-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETAMIDE;[N-METHOXYMETHYLAMINOCARBONYLMETHYLENE]-TRIPHENYLPHOSPHORANE;N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide, 98 %;(N-methoxymethylaminocarbonylmethylene)triphenylphosphoran;N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide 98%;N-methoxy-N-methyl-2-(triphenyl-l5-phosphanylidene)acetamide;Acetamide, N-methoxy-N-methyl-2-(triphenylphosphoranylidene)-
CAS:129986-67-0
MF:C22H22NO2P
MW:363.39
EINECS:
Product Categories:
Mol File:129986-67-0.mol
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Chemical Properties
Melting point 183 °C
Boiling point 495.6±28.0 °C(Predicted)
density 1.18±0.1 g/cm3(Predicted)
storage temp. -20°C Freezer, Under inert atmosphere
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
color Off White to Pale Yellow
BRN 4198472
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
9
HS Code 29241900
MSDS Information
ProviderLanguage
SigmaAldrich English
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Usage And Synthesis
Chemical PropertiesWhite to off-white powder
UsesReactant for:
  • Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
  • Phosphine-catalyzed asymmetric addition reactions
  • Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
  • Wittig olefination
  • Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Preparation Products And Raw materials
Raw materials2-BROMO-N-METHOXY-N-METHYL ACETAMIDE-->2-CHLORO-N-METHOXY-N-METHYLACETAMIDE-->Triphenylphosphine

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