| 2,2-Diethoxypropane Basic information |
| Product Name: | 2,2-Diethoxypropane |
| Synonyms: | 2,2-diethoxy-propan;Acetone diethyl ketal;acetonediethylketal;2,2-DIETHOXYPROPANE;ACETONE DIETHYL ACETAL;Propane, 2,2-diethoxy-;2,2-DIETHOXYPROPANE, TECH., 85%;2,2-DIETHOXYPROPANE 95+% |
| CAS: | 126-84-1 |
| MF: | C7H16O2 |
| MW: | 132.2 |
| EINECS: | 204-808-6 |
| Product Categories: | Organic Building Blocks;Oxygen Compounds;Acetals/Ketals/Ortho Esters;Building Blocks;Chemical Synthesis |
| Mol File: | 126-84-1.mol |
| 2,2-Diethoxypropane Chemical Properties |
| Boiling point | 116-117 °C (lit.) |
| density | 0.82 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 46 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| CAS DataBase Reference | 126-84-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Propane, 2,2-diethoxy-(126-84-1) |
| EPA Substance Registry System | Propane, 2,2-diethoxy- (126-84-1) |
| Safety Information |
| Hazard Codes | F |
| Risk Statements | 11 |
| Safety Statements | 16-29-33 |
| RIDADR | UN 3271 3/PG 2 |
| WGK Germany | 3 |
| RTECS | AL4900000 |
| TSCA | Yes |
| HazardClass | 3.1 |
| PackingGroup | II |
| HS Code | 29110000 |
| Toxicity | LD50 ipr-mus: 125 mg/kg NTIS** AD277-689 |
| MSDS Information |
| Provider | Language |
|---|---|
| Acetone diethyl acetal | English |
| SigmaAldrich | English |
| ALFA | English |
| 2,2-Diethoxypropane Usage And Synthesis |
| Preparation | To a flask equipped as in Preparation 2-11 and containing 1725 gm (37.5 moles) of ethanol, 18.4 gm (0.058 mole) of mercuric acetate, and 28 ml of 26% boron fluoride etherate (26%) at 30°C is added dropwise over a 15 min period at 45-50°C, 1250 gm (12.5 moles) of isopropenyl acetate. After the reaction 2200 gm of 25% sodium hydroxide is added, the organic layer separated, washed first with 400 ml of 0.01 Ν sodium hydroxide, dried, and distilled to afford 1140 gm (69%), b.p. 110-113 C (760 mm Hg). |
| Safety Profile | Poison by intraperitoneal route.When heated to decomposition it emits acrid smoke. |
| 2,2-Diethoxypropane Preparation Products And Raw materials |
| Preparation Products | ETHYL 2,2-DIETHOXYPROPIONATE-->Ethyl (R)-2-hydroxy-4-phenylbutyrate |
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