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| (2R)-(-)-GLYCIDYL 4-NITROBENZOATE Basic information |
| Product Name: | (2R)-(-)-GLYCIDYL 4-NITROBENZOATE | | Synonyms: | (2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate;4-nitrobenzoate,(r)-oxiranemethano;(R)-(-)-GLYCIDYL-4-NITROBENZOATE;(2R)-(-)-GLYCIDYL 4-NITROBENZOATE;GLYCIDYL4-NITROBENZOATE;(R)-(-)-Oxirane-2-methanol 4-nitrobenzoate;(R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate;2-Oxiranemethanol, 2-(4-nitrobenzoate), (2R)- | | CAS: | 106268-95-5 | | MF: | C10H9NO5 | | MW: | 223.18 | | EINECS: | | Product Categories: | | Mol File: | 106268-95-5.mol |
| (2R)-(-)-GLYCIDYL 4-NITROBENZOATE Chemical Properties |
| Melting point | 60-62 °C (lit.) | | storage temp. | 2-8°C | | optical activity | [α]19/D 37°, c = 1.08 in chloroform | | BRN | 5278590 |
| (2R)-(-)-GLYCIDYL 4-NITROBENZOATE Usage And Synthesis |
| Uses | (2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4. | | Purification Methods | Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] |
| (2R)-(-)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials |
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