4-Bromo-2,6-di-tert-butylphenol
4-Bromo-2,6-di-tert-butylphenol
  • CAS No.:1139-52-2
Other grades of this product :
4-Bromo-2,6-di-tert-butylphenol Basic information
Product Name:4-Bromo-2,6-di-tert-butylphenol
Synonyms:2,6-DI-TERT-BUTYL-4-BROMOPHENOL;4-BROMO-2,6-DI-T-BUTYLPHENOL;4-BROMO-2,6-DI-TERT-BUTYLPHENOL;4-BROMO-2,6-DI-TERT-PHENOL;Phenol, 4-bromo-2,6-bis(1,1-dimethylethyl)-;4-Bromo-2,6-bis(1,1-dimethylethyl)phenol;4-Bromo-2,6-di-tert-butylphenol,98%;4-Bromo-2,6-di-tert-butylphenol 98%
CAS:1139-52-2
MF:C14H21BrO
MW:285.22
EINECS:214-521-8
Product Categories:Organic Building Blocks;Oxygen Compounds;Aromatic Phenols;API intermediates;Phenols
Mol File:1139-52-2.mol
4-Bromo-2,6-di-tert-butylphenol Chemical Properties
Melting point 78-83 °C (dec.)(lit.)
Boiling point 128 °C / 4mmHg
density 1.2457 (rough estimate)
refractive index 1.5130 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol
pka11.23±0.40(Predicted)
form powder to crystal
color White to Orange to Green
BRN 2051052
CAS DataBase Reference1139-52-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
Hazard Note Irritant
HS Code 29081990
MSDS Information
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4-Bromo-2,6-di-tert-butylphenol English
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4-Bromo-2,6-di-tert-butylphenol Usage And Synthesis
Chemical Propertiesyellow to brown crystals
Uses4-Bromo-2,6-di-tert-butylphenol may be used in the following studies:
  • As a terminating comonomer phenol in the phase transfer catalyzed (PTC) polymerization of 4-bromo-2,6-dimethylphenol.
  • Synthesis of 1,1-[1,10-decanediylbis(oxy)]bis[(2,6-ditertbutyl-4-bromo)benzene], a monomer, which forms poly(p-phenylenevinylene) derivatives by reaction with 1,10-dibromodecane.
  • As a reactant in the synthesis of 2,6-di-tert-butyl-phenolnorbornene (NArOH), a norbornene comonomer bearing an antioxidant hindered phenol.
  • As a catalyst with methyl aluminium to form methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) which may be utilized for the transformation of various epoxides to carbonyl compounds.
General Description4-Bromo-2,6-di-tert-butylphenol is a 4-substituted-2,6-di-tert-butylphenol. It is synthesized by the bromination of 2,6-di-tert-butylphenol. The structure was confirmed by 1H NMR. Its photolysis reaction in benzene solution has been investigated. The photochemical reaction of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone has been studied by EPR spectroscopy.
4-Bromo-2,6-di-tert-butylphenol Preparation Products And Raw materials
Preparation Products3,3',5,5'-TETRA(TERT-BUTYL)[1,1'-BIPHENYL]-4,4'-DIOL

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