Melting point | 205-208 °C(lit.) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Soluble in acetone, benzene, dichloromethane, acetonitrile and tetrahydrofuran. |
form | Crystalline Powder |
color | Orange |
Sensitive | Moisture Sensitive |
Merck | 14,7974 |
BRN | 7054643 |
Exposure limits | OSHA: Ceiling 0.1 mg/m3 NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3 |
Stability: | Stable. May react with easily oxidized materials. Incompatible with reducing agents, combustible material, metals, strong reducing agents. |
InChIKey | LEHBURLTIWGHEM-UHFFFAOYSA-N |
CAS DataBase Reference | 26299-14-9(CAS DataBase Reference) |
EPA Substance Registry System | Pyridinium chlorochromate (26299-14-9) |
Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.
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