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| DIMETHYLSILYLDIETHYLAMINE Basic information |
| Product Name: | DIMETHYLSILYLDIETHYLAMINE | | Synonyms: | N,N-DIETHYL-1,1-DIMETHYLSILYLAMINE;DIETHYLAMINODIMETHYLSILANE;DIMETHYLSILYLDIETHYLAMINE;Silanamine,N,N-diethyl-1,1-dimethyl-;n,n-diethyl-1,1-dimethyl-silanamin;N,N-Diethyldimethylsilanamine;N,N-diethyl-1,1-dimethyl-Silanamine;N-dimethylsilyl-N-ethylethanamine | | CAS: | 13686-66-3 | | MF: | C6H17NSi | | MW: | 131.29 | | EINECS: | 237-202-5 | | Product Categories: | Chemical Synthesis;Organometallic Reagents;Organometallic Reagents;Organosilicon;Others | | Mol File: | 13686-66-3.mol |
| DIMETHYLSILYLDIETHYLAMINE Chemical Properties |
| Boiling point | 109 °C | | density | 0.8 | | refractive index | 1.4080 | | Fp | | solubility | sol common aprotic organic solvents. | | Specific Gravity | 0.8 | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | Sensitive | Moisture Sensitive | | BRN | 741862 | | EPA Substance Registry System | Silanamine, N,N-diethyl-1,1-dimethyl- (13686-66-3) |
| Hazard Codes | F,Xi | | Risk Statements | 11-36/37/38 | | Safety Statements | 16-23-26-36 | | RIDADR | 1993 | | WGK Germany | 3 | | TSCA | Yes | | HazardClass | 3 | | PackingGroup | II |
| Provider | Language |
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ALFA
| English |
| DIMETHYLSILYLDIETHYLAMINE Usage And Synthesis |
| Physical properties | bp 112°C/760 mmHg; n20
D 1.4087; d20
4 0.7505
g cm?3. | | Uses | N,N-Diethylaminodimethylsilane is a
useful reagent for the conversion of hydroxy groups of allyl
or homoallyl alcohols into hydrodimethylsilyl ethers for use in
intramolecular hydrosilation reactions. In some cases, N,N-diethylaminodimethylsilane
gives superior results compared to the
more commonly employed 1,1,3,3-tetramethyldisilazane (eq 1). | | Preparation | by treatment of commercially available
chlorodimethylsilane (ClMe2SiH) and diethylamine in the
presence of triethylamine in ether, followed by filtration and
distillation. |
| DIMETHYLSILYLDIETHYLAMINE Preparation Products And Raw materials |
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